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Reactions of Rubidium
Reactions with water
Rubidium metal reacts very rapidly with water to form a colourless solution of rubidium hydroxide (RbOH) and hydrogen gas (H2). The reaction is very exothermic. The resulting solution is basic because of the dissolved hydroxide. The reaction is so fast that if the reaction is carried out in a glass vessel, the glass container may well shatter. The reaction is slower than that of caesium (below rubidium in the periodic table), but faster than that of potassium (above rubidium in the periodic table).
  2Rb(s) + 2H2O22RbOH(aq) + H2(g)
Reactions with air
Rubidium is very soft and easily cut, the resulting surface is bright and shiny. However, this surface soon tarnishes because of reaction with oxygen and moisture from the air. If rubidium is burned in air, the result is mainly formation of dark brown rubidium superoxide, RbO2.
  Rb(s) + O2(g)RbO2(s)
Reactions with halogens
Rubidium metal reacts vigorously with all the halogens to form rubidium(I) halides.
  2Rb(s) + F2(g)2RbF(s)
  2Rb(s) + Cl2(g)2RbCl(s)
  2Rb(s) + Br2(g)2RbBr(s)
  2Rb(s) + I2(g)2RbI(s)
Reactions with acids
Rubidium metal dissolves readily in dilute sulphuric acid (H2SO4) to form solutions containing the Rb(I) ion together with hydrogen gas, H2.
2Rb(s) + H2SO42Rb+(aq) + SO42-(aq) + H2(g)
Reactions with bases
Rubidium metal reacts very rapidly with water to form a colourless basic solution of rubidium hydroxide (RbOH) and hydrogen gas (H2). The reaction continues even when the solution becomes basic. The resulting solution is basic because of the dissolved hydroxide. As the reaction proceeds, the concentration of base increases. The reaction is very exothermic. The reaction is so fast that if the reaction is carried out in a glass vessel, the glass container may well shatter! The reaction is slower than that of caesium (below rubidium in the periodic table), but faster than that of potassium (above rubidium in the periodic table).
  2Rb(s) + 2H2O2RbOH(aq) + H2(g)
 
Reduction Potentials
Balanced half-reaction E0 / V
Rb+ + e-Rb(s) -2.93